The interactions between wax and UF resin in medium density fibreboardWechselbeziehungen zwischen Wachs und UF-Harz in mitteldichten Faserplatten

被引:1
作者
Warren Grigsby
Armin Thumm
机构
[1] Scion,Science Leader
关键词
Internal Bond; Urea Formaldehyde; Fibre Wall; Urea Formaldehyde; Internal Bond Strength;
D O I
10.1007/s00107-011-0580-9
中图分类号
学科分类号
摘要
Through the use of fluorescently labelled paraffin wax and UF resin, fluorescence microscopy has been used to simultaneously visualise wax and resin components on medium density fibreboard (MDF) fibre. To simulate differing application methods, the wax and resin were applied to fibre either separately or as a mixture. Visualisation on unpressed fibre and in panels suggests the application order can lead to differing wax-resin behaviours and how each interact with fibre. Both qualitative and quantitative analyses of wax and resin distribution on fibre established that the main differences in behaviours were due to wax and occur on pressing. Applying wax first to fibre led to wax droplet agglomeration in panels whereas applying wax after resin or as a mixture appeared to allow wax to be retained as relatively smaller droplets within the resin matrix. This also manifested itself in differences in wax overlap with resin in panels, where a relatively low overlap was observed when applying wax first, despite a substantially higher overlap in unpressed fibre. Application of wax after resin or as a mixture resulted in the wax generally staying with the resin. The observed differences in wax distribution were also correlated with panel cold water soak properties.
引用
收藏
页码:507 / 517
页数:10
相关论文
共 34 条
[1]  
Dix B(2005)On paraffin sizing of medium density fiberboards (MDF). Part 1: Influence of the chemical composition of paraffin and type of emulsifier on the hydrophobic properties of MDF Holz Roh- Werkst 63 192-203
[2]  
Roffael E(1989)Adhesive/fiber interaction in medium density fiberboard Wood Sci Technol 23 371-380
[3]  
Schneider T(2004)X-ray photoelectron spectroscopy determination of resin coverage on MDF fiber Holz Roh- Werkst 62 358-68
[4]  
Donaldson LA(2011)Resin and wax distribution and mobility during medium density fibreboard manufacture Eur J Wood Prod. 46 63-380
[5]  
Lomax TD(1996)Measurement of resin and wax distribution on wood flakes For Prod J 35 370-148
[6]  
Grigsby WJ(2003)Resin distribution in medium density fiberboard, quantification of UF resin distribution on blowline blended MDF fiber and panels Wood Fiber Sci 42 133-470
[7]  
McDonald AM(2008)Quantification of urea formaldehyde resin in wood fibers using X-ray photoelectron spectroscopy and confocal laser scanning microscopy Wood Sci Technol 61 469-277
[8]  
Thumm A(2003)Paraffins of different chain lengths as water repellent in medium-density board (MDF) Holz Roh- Werkst 63 272-284
[9]  
Loxton C(2005)On paraffin sizing of medium density fiberboards (MDF) Part 2: Influence of resination process (blender and blowline technique) and method of adding paraffin dispersion within the blender- and blowline-process on paraffin sizing of medium density fibreboards (MDF) 2005 Holz Roh- Werkst 63 278-undefined
[10]  
Grigsby WJ(2005)On paraffin sizing of medium density fibreboards (MDF). Part 3: Methods for evaluation of paraffin sizing on thermo-mechanical pulps Holz Roh- Werkst 46 56-undefined