R-Enantioselective galactosylation of secondary alcohols using b-galactosidase

被引：2

作者：

Shuichi Matsumura

Hiroki Yamazaki

Kazunobu Toshima

机构：

[1] Keio University,Department of Applied Chemistry, Faculty of Science and Technology

来源：

Biotechnology Letters | 1997年 / 19卷

关键词：

Alcohol; Organic Chemistry; Bioorganic Chemistry; Secondary Alcohol;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Significant R-enantioselection occurred for b-galactosyl transfer to the secondary alcohols, 2-butanol, 2-octanol, 3-methyl-2-butanol, 1-phenylethanol, 1,2-propanediol, 1-methoxy-2-propanol and 3-hydroxybutanoates, with b-galac-tosidase from Escherichia coli. The highest R-enantioselection of 98% e.e. was for the b-galactosylation of 1-phenylethanol using b-galactosidase from E. coli.

引用

页码：583 / 586

页数：3

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