[2 + 2] CYCLOADDITIONS OF 2,2-BIS(TRIFLUOROMETHYL)ETHYLENE-1,1-DICARBONITRILE WITH ENOL ETHERS, 1,1-DIMETHYLBUTADIENE, AND ALLYLTRIMETHYLSILANE

被引：20

作者：

HUISGEN, R

BRUCKNER, R

机构：

[1] Institut für Organische Chemie der Universität München, 8000 München 2

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 18期

关键词：

D O I：

10.1016/0040-4039(90)80123-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Vinyl ethers and the title compound (BTF) form cyclobutanes via 1,4-dipoles which can be intercepted with ethanol or acetic acid. Cis- and trans-1-ethoxypropene react with BTF nonstereospecifically in agreement with a stepwise mechanism. 1,1-Dimethylbutadiene or allyltrimethylsilane undergo [2 + 2] cycloadditions with BTF, too. © 1990.

引用

页码：2553 / 2556

页数：4

共 29 条

[1]

BARTLETT PD, 1979, Q REV, V24, P473

[2] CYANOCARBON CHEMISTRY .23. IONIZATION BEHAVIOR OF CYANOCARBON ACIDS [J].