NEW POLYFLUOROALKOXYSULFONYL FLUORIDES .2.

被引：14

作者：

CHEN, LF

MOHTASHAM, J

GARD, GL

机构：

[1] Department of Chemistry, Portland State University, Portland

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1990年 / 46卷 / 01期

关键词：

D O I：

10.1016/S0022-1139(00)81558-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of CF2CF2OSO2 with haloalkanes (RX, X = I, Br) in the presence of metal fluorides, MF (M = Cs+, Ag+) was studied as a means for preparing novel reactive polyfluoroalkoxysulfonyl fluorides. The following compounds have been prepared and characterized: ROCF2CF2SO2F where R = OCH2CHCH2, (CH3)3SiCH2, (CF3)2CFCH2CH2, HCCCH2, BrCH=CHCH2 (cis and trans), CH2=CBrCH2, (CH3CH2O)2P(O)CH2CH2, CH3CH2OPF(O)CH2CH2. Infrared, mass and nmr spectra are presented in order to support the assigned structures. © 1990.

引用

页码：39 / 56

页数：18

共 10 条

[1]

BROWN JK, 1965, ADV FLUORINE CHEM, V4, P256

[2] SYNTHESIS OF 3 PARTIALLY FLUORINATED ALKANESULFONIC ACIDS AS POTENTIAL FUEL-CELL ELECTROLYTES [J].