STUDIES ON PHOTODEGRADATION OF POLYVINYL-CHLORIDE) .3.

被引:10
作者
MORI, F [1 ]
KOYAMA, M [1 ]
OKI, Y [1 ]
机构
[1] TOYO SEIKAN GRP,CORP RES & DEV,HODOGAYA KU,YOKOHAMA,JAPAN
来源
ANGEWANDTE MAKROMOLEKULARE CHEMIE | 1979年 / 75卷 / FEB期
关键词
D O I
10.1002/apmc.1979.050750108
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
PVC films were degraded by outdoor exposure, irradiation by a weatherometer and heating by an electric oven. In PVC films subjected to outdoor exposure and to irradiation by the weatherometer at a low temperature, e. g. sample surface temperature of 0°C, photo‐oxidation and scission of the main chain were caused, but dehydrochlorination or formation of solvent‐insoluble substances were not observed. In contrast, PVC subjected to irradiation by the weatherometer at a high temperature, e. g. sample surface temperature of 80°C, showed a degradation tendency similar to that of PVC heated at 200°C in the electric oven, and decomposition of the thermal degradation type characterized by dehydrochlorination, formation of polyenes and formation of solvent‐insoluble substances were observed. © 1979 Hüthig & Wepf Verlag, Basel
引用
收藏
页码:113 / 122
页数:10
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MORI, F ;
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ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1977, 64 (SEP) :89-99
[10]   STUDIES ON PHOTODEGRADATION OF POLYVINYL-CHLORIDE) .2. [J].
MORI, F ;
KOYAMA, M ;
OKI, Y .
ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1978, 68 (MAY) :137-148