TOWARDS THE TOTAL SYNTHESIS OF CLERODIN .1.

被引：9

作者：

BOUCHARD, H ^{[1
]}

RENARD, PY ^{[1
]}

LALLEMAND, JY ^{[1
]}

机构：

[1] ECOLE POLYTECH,SYNTHESE ORGAN LAB,F-91128 PALAISEAU,FRANCE

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 42期

关键词：

CLERODIN; ANTIFEEDANT; STEREOSPECIFIC CLAISEN REARRANGEMENT; QUATERNARY ASYMMETRIC CARBON; TERPENE;

D O I：

10.1016/S0040-4039(00)79435-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A highly stereo- and enantioselective approach to clerodin 1, an insect antifeedant, is described. The key step involved the stereospecific formation of the C-9-C-11 bond, at an early stage of the synthesis, using a Claisen rearrangement.

引用

页码：5953 / 5956

页数：4

共 19 条

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