DIENYL COMPLEXES OF TRANSITION METALS .I. ADDITION OF HYDRIDE TO METHYL-SUBSTITUTED ARENECYCLOPENTADIENYLIRON CATIONS

被引:135
作者
KHAND, IU
PAUSON, PL
WATTS, WE
机构
来源
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1968年 / 17期
关键词
D O I
10.1039/j39680002257
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The addition of hydride to a series of methyl-substituted arenecyclopentadienyliron cations has been shown to occur exclusively at the arene ring, giving π-cyclohexadienyl derivatives. The methyl substituents influence the mode of reaction only insofar as hydride addition to an unsubstituted arene carbon is preferred. The 1H n.m.r. spectra of these compounds are discussed.
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页码:2257 / &
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