[(ETA-5-CP)2SN(MU-ETA-5-CP)NA.PMDETA], A COMPOUND WITH A TRIGONAL-PLANAR PADDLE WHEEL TRIORGANOSTANNATE ION

被引：41

作者：

DAVIDSON, MG

STALKE, D

WRIGHT, DS

机构：

[1] UNIV CAMBRIDGE, CHEM LAB, LENSFIELD RD, CAMBRIDGE CB2 1EW, ENGLAND

[2] INST ANORGAN CHEM, W-3400 GOTTINGEN, GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1992年 / 31卷 / 09期

关键词：

D O I：

10.1002/anie.199212261

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An organotin(II) anion with three η5‐Cp ligands and a Sn atom in a trigonal‐planar environment are found in the title compound 1 (see diagram), obtained from the reaction of CpNa, [Cp2Sn], and PMDETA (mol ratio 1:1:1). This [Cp3Sn]− ion is linked to the Na+ ion by a μ‐η5‐Cp bridge. Compound 1 is a polymeric array in the solid state due to intermolecular C(H) … Na interactions. PMDETA = (Me2NCH2CH2)2NMe. (Figure Presented.) Copyright © 1992 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1226 / 1227

页数：2

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