POLYMER-MONOMER AND POLYMER-POLYMER INTERACTIONS AND THEIR EFFECT ON THE STABILITY OF EMULSIFIER-FREE ACRYLATE LATEXES

被引：10

作者：

ASLAMAZOVA, T

BOGDANOVA, S

机构：

[1] Institute of Physical Chemistry, Russian Academy of Sciences, 117915 Moscow, Leninsky prospect

来源：

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 1995年 / 104卷 / 2-3期

关键词：

ACRYLATE; EMULSIFIER-FREE; INTERACTION; LATEX; METHACRYLATE; MONOMER; MONOMERIC ACID; POLYMER; POLYMERIZATION; STABILITY;

D O I：

10.1016/0927-7757(95)03263-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effects of water soluble (acrylic and methacrylic acids) and highly hydrophilic (methyl acrylate) comonomers on the stability of emulsifier-free latexes (EFL) of hydrophobic monomers (styrene, butyl acrylate) have been studied. Stability of the latex increases with increasing concentration of monomeric acid, whereas there is a region of maximum stability in the case of methyl acrylate. The effects observed are explained by the difference in polymer-monomer (p/m) and polymer-polymer (p/p) interactions for the two types of comonomers.

引用

页码：147 / 155

页数：9

共 24 条

[1]

Aslamazova T. P., 1987, VYSOKOMOL SOEDIN A, V29, P434

[2]

ASLAMAZOVA TR, 1992, KOLLOID ZH, V54, P3

[3]

ASLAMAZOVA TR, 1994, KOLLOID ZH, V56, P309

[4]

DERJAGUIN BV, 1987, LANGMUIR, V3, P607

[5]

DERJAGUIN BV, 1985, SURFACE FORCES, P244

[6]

DUNN AS, 1970, BRIT POLYM J, V2, P49, DOI DOI 10.1002/(ISSN)1934-256X

[7]

ELISEEVA VI, 1976, VYSOKOMOL SOEDIN A+, V18, P1141

[8]

ELISEEVA VI, 1991, USP KHIM+, V60, P398

[9]

ELISEEVA VI, 1991, KOLLOID ZH, V53, P21

[10]

ELISEEVA VI, 1965, DOKL AKAD NAUK SSSR, V162, P1085

← 1 2 3 →