COMPARISON OF A PRIMITIVE MODEL PERTURBATION-THEORY WITH EXPERIMENTAL-DATA OF SIMPLE ELECTROLYTES

被引：16

作者：

CHAN, KY

机构：

[1] Department of Chemistry, University of Hong Kong, Hong Kong, Pokfulam Road

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 22期

关键词：

D O I：

10.1021/j100385a022

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Perturbation theory of the restricted primitive model is applied to some simple electrolytes and compared with experimental data of activity coefficients. The theory fits the data well with only one parameter, the diameter of the ion. However, the fitted diameter is inconsistent with Pauling's diameter. © 1990 American Chemical Society.

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页码：8472 / 8477

页数：6

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