FUNCTIONAL CARBONATES - CYCLIC ALPHA-METHYLENE CARBONATES AND BETA-OXOPROPYL CARBONATES FROM PROP-2-YNYL ALCOHOL DERIVATIVES AND CO2

被引：81

作者：

JOUMIER, JM ^{[1
]}

FOURNIER, J ^{[1
]}

BRUNEAU, C ^{[1
]}

DIXNEUF, PH ^{[1
]}

机构：

[1] UNIV RENNES 1,CHIM COORDINAT ORGAN LAB,CNRS,URA 415,CAMPUS BEAULIEU,F-35042 RENNES,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1991年 / 12期

关键词：

D O I：

10.1039/p19910003271

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The phosphine-catalysed synthesis of cyclic-alpha-methylene carbonates 2 directly from prop-2-ynyl alcohol derivatives and CO2 is described. These cyclic carbonates 2 are key intermediates for the selective access to beta-oxopropyl carbonates 3 by reaction with alcohols under mild conditions, but in the presence of Et3N or KCN as catalyst.

引用

页码：3271 / 3274

页数：4

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