SYNTHESIS OF COREY LACTONE VIA HIGHLY STEREOSELECTIVE ASYMMETRIC DIELS-ALDER REACTION

被引：17

作者：

MIYAJI, K ^{[1
]}

OHARA, Y ^{[1
]}

TAKAHASHI, Y ^{[1
]}

TSURUDA, T ^{[1
]}

ARAI, K ^{[1
]}

机构：

[1] NISSAN CHEM IND CO LTD,CENT RES INST,FUNABASHI,CHIBA 274,JAPAN

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 35期

关键词：

D O I：

10.1016/0040-4039(91)80038-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We have succeeded in a highly stereoselective asymmetric Diels-Alder reaction between a chiral acrylate 3a derived from commercially available D-pantolactone 2 and 5-benzyloxymethyl-cyclopentadiene 4 to give the adduct 5a in 94% d.e. and 79% yield for the synthesis of Corey lactone 1.

引用

页码：4557 / 4560

页数：4

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