STUDIES ON ORGANOLANTHANIDE COMPLEXES .41. CATALYTIC ISOMERIZATION OF OLEFINS BY ORGANOLANTHANIDE COMPLEX SODIUM HYDRIDE SYSTEMS

被引：31

作者：

QIAN, CT

ZHU, DM

LI, DM

机构：

[1] Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, 200032

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 430卷 / 02期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/0022-328X(92)86005-O

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Isomerization of several 1-alkenes catalyzed by organolanthanide complex/sodium hydride systems in THF at 45-degrees-C, affords cis- and trans-2-alkenes in excellent yields. Effects of solvent and pi-ligand of complex on this isomerization are also examined. The catalytic isomerization may occur via organolanthanide hydride intermediate.

引用

页码：175 / 180

页数：6

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