CHEMISTRY OF ORGANOMETAL METALLACYCLIC SUBGROUP METAL-COMPOUNDS .5. SYNTHESIS OF LI2NI(CH2CH2CH2CH2)2(SOLV)X FROM K[NI(NPH2)3](THF) AND LICH2CH2CH2CH2LI - MOLECULAR-STRUCTURE OF (LI(THF)2)2NI(CH2CH2CH2CH2)2

被引：21

作者：

FROHLICH, HO ^{[1
]}

WYRWA, R ^{[1
]}

GORLS, H ^{[1
]}

机构：

[1] UNIV JENA,MAX PLANCK GESELL,ARBEITSGRUPPE CO2 CHEM,O-6900 JENA,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 441卷 / 02期

关键词：

D O I：

10.1016/0022-328X(92)83376-S

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new synthetic route to Li2Ni(C4H8)2(Solv)x (Solv = diethylether, Et2O, x = 1 (1); tetramethylethylendiamin, TMED, x = 2 (2); tetrahydrofuran, THF, x = 4 (3)) is described. (Li(THF)2)2Ni(C4H8)2 (3) has been characterized by X-ray studies. The H-1 and C-13 NMR spectral properties of the metallacycles are reported.

引用

页码：169 / 175

页数：7