SYNTHESIS AND MOLECULAR-STRUCTURE OF BIS-(3-DIMETHYLAMINOPROPYLALANE)

被引：21

作者：

DUMICHEN, U

THIELE, KH

GELBRICH, T

SIELER, J

机构：

[1] UNIV HALLE WITTENBERG,INST ANORGAN CHEM,D-06217 MERSEBURG,GERMANY

[2] UNIV LEIPZIG,INST ANORGAN CHEM,D-04103 LEIPZIG,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 495卷 / 1-2期

关键词：

ALUMINUM; ALANES; NMR SPECTROSCOPY; X-RAY DIFFRACTION;

D O I：

10.1016/0022-328X(95)05418-O

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Me(2)NCH(2)CH(2)CH(2)Li reacts with AlCl3 with formation of Cl(2)AlCH2CH(2)CH(2)NMe(2) II which can be transferred into Bis(3-dimethylaminopropylalane), [H(2)AlCH(2)CH(2)CH(2)NMe(2)](2) III by means of LiH. III can be obtained also by intramolecular hydroalumination reaction of the complex H3Al <-- NMe(2)CH(2)CH=CH2 IV. MS, H-1, C-13 and Al-27 NMR spectra and the X-ray structure of III are reported and discussed.

引用

页码：71 / 75

页数：5

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