A ROOM-TEMPERATURE LUMINESCENT CYCLOMETALLATED RUTHENIUM(II) COMPLEX OF 6-PHENYL-2,2'-BIPYRIDINE

被引：73

作者：

COLLIN, JP ^{[1
]}

BELEY, M ^{[1
]}

SAUVAGE, JP ^{[1
]}

BARIGELLETTI, F ^{[1
]}

机构：

[1] CNR,IST FRAE,I-40126 BOLOGNA,ITALY

来源：

INORGANICA CHIMICA ACTA | 1991年 / 186卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)87936-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cyclometallated complex Ru(tt)(phbp)+ (tt = 4'-tolyl-2,2':6'2"-terpyridine, phbp = 6-phenyl-2,2'-bipyridine) with a (N,N,N)(C,N,N) coordination, has been synthesized and characterized by H-1 NMR, UV, FAB-MS spectral techniques and by elemental analysis. We have compared its electrochemical and photophysical properties with those of the non-orthometallated analogues Ru(tt)2(2+) and Ru(terpy)2(2+) (terpy = 2,2':6',2"-terpyridine). The most remarkable feature of Ru(tt)(phbp)+ is its ability to luminesce at room temperature in alcoholic and nitrile solvents. The lifetime of its 3MLCT excited state is 60 ns in CH3CN.

引用

页码：91 / 93

页数：3

共 16 条

[1] SYNTHETIC CONTROL OF EXCITED-STATE PROPERTIES - TRIS-CHELATE COMPLEXES CONTAINING THE LIGANDS 2,2'-BIPYRAZINE, 2,2'-BIPYRIDINE, AND 2,2'-BIPYRIMIDINE
ALLEN, GH
WHITE, RP
RILLEMA, DP
MEYER, TJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (09) : 2613 - 2620
[2] [Anonymous], 1969, DATA REDUCTION ERROR
[3] METALLOPOLYMER PHOTOCHEMISTRY - PHOTOPHYSICAL, PHOTOCHEMICAL, AND PHOTO-ELECTROCHEMICAL PROPERTIES OF (BPY)2RUII LESS-THAN SITES BOUND TO POLY(4-VINYLPYRIDINE)
CALVERT, JM
CASPAR, JV
BINSTEAD, RA
WESTMORELAND, TD
MEYER, TJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (24) : 6620 - 6627
[4] PHOTOCHEMISTRY OF MLCT EXCITED-STATES - EFFECT OF NONCHROMOPHORIC LIGAND VARIATIONS ON PHOTOPHYSICAL PROPERTIES IN THE SERIES CIS-RU(BPY)2L22+
CASPAR, JV
MEYER, TJ
[J]. INORGANIC CHEMISTRY, 1983, 22 (17) : 2444 - 2453
[5] CYCLOPALLADATED AND CYCLOPLATINATED COMPLEXES OF 6-PHENYL-2,2'-BIPYRIDINE - PLATINUM PLATINUM INTERACTIONS IN THE SOLID-STATE
CONSTABLE, EC
HENNEY, RPG
LEESE, TA
TOCHER, DA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (06) : 513 - 515
[6] CYCLOMETALLATION REACTIONS OF 6-PHENYL-2,2'-BIPYRIDINE - A POTENTIAL C,N,N-DONOR ANALOG OF 2,2'-6',2''-TERPYRIDINE - CRYSTAL AND MOLECULAR-STRUCTURE OF DICHLOROBIS(6-PHENYL-2,2'-BIPYRIDINE)RUTHENIUM(II)
CONSTABLE, EC
HENNEY, RPG
LEESE, TA
TOCHER, DA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (02): : 443 - 449
[7] A CYCLOMETALLATED ANALOG OF TRIS(2,2'-BIPYRIDINE)RUTHENIUM(II)
CONSTABLE, EC
HOLMES, JM
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 301 (02) : 203 - 208
[8] DIRECT SYNTHESIS OF DISUBSTITUTED AROMATIC POLYIMINE CHELATES
DIETRICHBUCHECKER, CO
MARNOT, PA
SAUVAGE, JP
[J]. TETRAHEDRON LETTERS, 1982, 23 (50) : 5291 - 5294
[9] RU(II) POLYPYRIDINE COMPLEXES - PHOTOPHYSICS, PHOTOCHEMISTRY, ELECTROCHEMISTRY, AND CHEMI-LUMINESCENCE
JURIS, A
BALZANI, V
BARIGELLETTI, F
CAMPAGNA, S
BELSER, P
VONZELEWSKY, A
[J]. COORDINATION CHEMISTRY REVIEWS, 1988, 84 : 85 - 277
[10] MECHANISM OF QUENCHING OF EMISSION OF SUBSTITUTED POLYPYRIDINERUTHENIUM(II) COMPLEXES BY IRON(III), CHROMIUM(III), AND EUROPIUM(III) IONS
LIN, CT
BOTTCHER, W
CHOU, M
CREUTZ, C
SUTIN, N
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (21) : 6536 - 6544

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