ASYMMETRIC HECK REACTION-ANION CAPTURE PROCESS - A CATALYTIC ASYMMETRIC-SYNTHESIS OF THE KEY INTERMEDIATES FOR THE CAPNELLENOLS

被引：71

作者：

KAGECHIKA, K

OHSHIMA, T

SHIBASAKI, M

机构：

[1] UNIV TOKYO,FAC PHARMACEUT SCI,BUNKYO KU,TOKYO 113,JAPAN

[2] HOKKAIDO UNIV,FAC PHARMACEUT SCI,SAPPORO,HOKKAIDO 060,JAPAN

来源：

TETRAHEDRON | 1993年 / 49卷 / 09期

关键词：

D O I：

10.1016/S0040-4020(01)80534-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A catalytic asymmetric synthesis of the key intermediates 4 and 15 for the capnellenols has been achieved through an asymmetric Heck reaction followed by the acetate anion capture process. Furthermore, the above reaction has been successfully applied to an asymmetric Heck reaction -amine capture process.

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页码：1773 / 1782

页数：10

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