CATALYTIC ACTIVITY OF POLYMERIZABLE METAL BETA-KETOESTERATO COMPLEXES TOWARDS MICHAEL ADDITION-REACTIONS

被引：13

作者：

MASTRORILLI, P ^{[1
]}

NOBILE, CF ^{[1
]}

SURANNA, GP ^{[1
]}

机构：

[1] POLITECN BARI,IST CHIM,CNR,CTR STUDI METODOL INNOVAT SINTESI ORGAN,I-70126 BARI,ITALY

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1995年 / 103卷 / 01期

关键词：

COBALT; MICHAEL ADDITION; KETOESTERATE; NICKEL; POLYMER SUPPORT; SUPPORTED CATALYSTS;

D O I：

10.1016/1381-1169(95)00095-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The addition of beta-dioxygenato compounds to methyl vinyl ketone was catalysed by nickel(II) and cobalt(II) complexes with the polymerizable beta-ketoesterato 2-(acetoacetoxy)ethyl methacrylate (AAEMA(-)) under homogeneous and heterogeneous phases. The homogeneous reactions were carried out using the soluble Ni(AAEMA)(2) and Co(AAEMA)(2) complexes whereas the heterogeneous catalytic tests were carried out using the copolymers obtained by reaction of M(AAEMA)(2) (M=Ni or Co) with suitable acrylamides.

引用

页码：23 / 29

页数：7

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