THE SYSTEM CARBON DIOXIDE-WATER AND THE KRICHEVSKY-KASARNOVSKY EQUATION

被引:89
作者
CARROLL, JJ
MATHER, AE
机构
[1] Department of Chemical Engineering, University of Alberta, Edmonton, T6G 2G6, Alberta
关键词
HENRY LAW; SOLUBILITY; KRICHEVSKY EQUATION; CARBON DIOXIDE-WATER;
D O I
10.1007/BF00650756
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The system carbon dioxide-water has been studied often. However, there is some controversy about the thermodynamic description of the behavior of this system. Some researchers indicate that the system CO2-H2O is accurately modeled by the Krichevsky-Kasarnovsky equation. Others say that it is not. This paper investigates this controversy. As a part of this study an overview of Henry's law and a discussion of the limitations of the Krichevsky-Kasarnovsky equation are preserved. From the analysis presented in this paper, it must be concluded that for temperatures lower than about 100-degrees-C, the system CO2-H2O is accurately modeled by the Krichevsky-Kasarnovsky equation. On the other hand, at 100-degrees-C and higher, it is not. In order to arrive at this conclusion, four models of the solubility were investigated. Using these models, it is clearly demonstrated that the activity coefficients are not negligible and hence the Krichevsky-Kasarnovsky equation is not applicable at high temperatures.
引用
收藏
页码:607 / 621
页数:15
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