SYNTHESIS AND STRUCTURE OF THE PHOSPHORANE P(CH2CL)CL4

被引：9

作者：

DILLON, KB

STRAW, TA

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 04期

关键词：

D O I：

10.1039/c39910000234

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The compound P(CH2Cl)Cl4, which is molecular in the liquid phase, has been shown by solid-state P-31 MAS NMR spectroscopy to have the structure [P(CH2Cl)Cl3]+[P(CH2Cl)Cl5]-; this is the first example of an organochlorophosphorane having a structure like that of solid [PCl4]+[PCl6]-.

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页码：234 / 235

页数：2

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