HETEROBIMETALLIC COMPLEXES BRIDGED BY A SINGLE 4E SULFUR LIGAND - ADDITION OF M'(CO)(5) (M'=CR, MO, W) TO THE TA=S BOND OF (T-BUC(5)H(4))(2)TA(S)H

被引：12

作者：

BRUNNER, H

CHALLET, S

KUBICKI, MM

LEBLANC, JC

MOISE, C

VOLPATO, F

WACHTER, J

机构：

[1] UNIV BOURGOGNE,SYNTH & ELECTROSYNTH ORGAN MET LAB,URA 1685,F-21100 DIJON,FRANCE

[2] UNIV REGENSBURG,INST ANORGAN CHEM,D-93040 REGENSBURG,GERMANY

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 08期

关键词：

D O I：

10.1021/om00008a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of Cp'Ta-2(=S)H with M'(CO)(5)(THF) (M' = Cr, Mo, W) gives rise to the formation of adducts in which the M'(CO)(5) fragments are coordinated to the Ta-S double bond as established by means of H-1 NMR and, in the case of M' = W, by X-ray diffraction data.

引用

页码：3623 / 3624

页数：2

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