RESONANCE-ENHANCED MULTIPHOTON IONIZATION OF HG(NH3)M AND HG2(NH3)M CLUSTERS PRODUCED IN A SUPERSONIC JET

被引：9

作者：

DEDONDERLARDEUX, C

JOUVET, C

RICHARDVIARD, M

SOLGADI, D

机构：

[1] Laboratoire de Photophysique Moléculaire, CNRS, Université de Paris Sud, 91405 Orsay Cedex

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 170卷 / 2-3期

关键词：

D O I：

10.1016/0009-2614(90)87107-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ionization and fragmentation of Hgn=1,2 (NH3)m=1-6 clusters are studied by resonance-enhanced multiphoton ionization. For m ≥ 2, the ionization threshold of Hg2(NH3)m is higher than that of Hg(NH3)m. Fragmentation channels in the ionic clusters are different: Hg(NH3)m+ clusters dissociate to Hg(NH3)m-x+ + (NH3)x, whereas the fragmentation of Hg2(NH3)m+ clusters leads to ionic ammonia clusters (NH3)m+ and (NH3)mH+. © 1990.

引用

收藏

页码：153 / 160

页数：8

相关论文

共 21 条

[1] INTRACLUSTER REACTIONS IN PHENYLACETYLENE AMMONIA CLUSTERS INITIATED THROUGH RESONANT ENHANCED IONIZATION [J].

BREEN, JJ ;

TZENG, WB ;

KILGORE, K ;

KEESEE, RG ;

CASTLEMAN, AW .

JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (01) :19-24

[2] SPECTROSCOPY OF PHENYLACETYLENE BOUND TO CLUSTERS OF AMMONIA AND THE SURFACE CLUSTER ANALOGY [J].

BREEN, JJ ;

KILGORE, K ;

TZENG, WB ;

WEI, S ;

KEESEE, RG ;

CASTLEMAN, AW .

JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (01) :11-18

[3]

CASTLEMAN AW, 1986, IN PRESS J CHEM SOC

[4] ENERGETICS OF GAS-PHASE PROTON SOLVATION BY NH3 [J].

CEYER, ST ;

TIEDEMANN, PW ;

MAHAN, BH ;

LEE, YT .

JOURNAL OF CHEMICAL PHYSICS, 1979, 70 (01) :14-17

[5] SUPERSONIC MOLECULAR-BEAM MASS-SPECTROMETRIC STUDY OF HYDROGEN BONDING IN AMMONIA [J].

COOK, KD ;

TAYLOR, JW .

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 1979, 30 (3-4) :345-357

[6] HALF-COLLISION STUDIES OF THE HG-NH3 EXCIMER [J].

DUVAL, MC ;

SOEP, B ;

VANZEE, RD ;

BOSMA, WB ;

ZWIER, TS .

JOURNAL OF CHEMICAL PHYSICS, 1988, 88 (04) :2148-2158

[7] MULTIPHOTON IONIZATION OF AMMONIA CLUSTERS AND THE DISSOCIATION DYNAMICS OF PROTONATED CLUSTER IONS [J].

ECHT, O ;

DAO, PD ;

MORGAN, S ;

CASTLEMAN, AW .

JOURNAL OF CHEMICAL PHYSICS, 1985, 82 (09) :4076-4085

[8]

JOUVET C, IN PRESS J PHYS CHEM

[9] THEORETICAL-STUDY OF THE AMMONIATED NH4 RADICAL AND RELATED STRUCTURES [J].

KASSAB, E ;

EVLETH, EM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (06) :1653-1661

[10] SOLVENT SHIFTS IN VANDERWAALS COMPLEXES OF PERYLENE [J].

KETTLEY, JC ;

ORAM, JW ;

PALMER, TF ;

SIMONS, JP ;

AMOS, AT .

CHEMICAL PHYSICS LETTERS, 1987, 140 (03) :286-292