FORMATION OF NOVEL BIDENTATE AND CROWN THIOETHER LIGANDS VIA DICOBALT ALKYNE COMPLEXES

被引：25

作者：

GELLING, A

JEFFERY, JC

POVEY, DC

WENT, MJ

机构：

[1] UNIV KENT,CHEM LAB,CANTERBURY CT2 7NH,KENT,ENGLAND

[2] UNIV BRISTOL,DEPT INORGAN CHEM,BRISTOL BS8 1TS,AVON,ENGLAND

[3] UNIV SURREY,DEPT CHEM,GUILDFORD GU2 5XH,SURREY,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 06期

关键词：

D O I：

10.1039/c39910000349

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Open chain and cyclic thioalkyne complexes capable of ligating metal-carbonyl moieties are prepared by the reaction of [Co2(mu-HOCH2C = CCH2OH)(CO)6] with mono- and di-thiols in the presence of HBF4 and the structures of [Co2(CO)4(mu-dppm){mu-C2(CH2SMe)2}Mo(CO)4] and [Co2{mu-C2(CH2SCH2CH2)2S}(CO)6] have been established by X-ray crystallography; dppm = bis(diphenylphosphino)methane.

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页码：349 / 351

页数：3

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