AEROSOLS FORMED FROM THE CHEMICAL-REACTION OF MONOTERPENES AND OZONE

被引：128

作者：

YOKOUCHI, Y

AMBE, Y

机构：

[1] The Division of Chemistry and Physics, National Institute for Environmental Studies, Yatabe, Ibaraki 305, Japan

来源：

ATMOSPHERIC ENVIRONMENT | 1985年 / 19卷 / 08期

关键词：

CHROMATOGRAPHIC ANALYSIS - Gas - HYDROCARBONS - Chemical Reactions - OZONE - Chemical Reactions;

D O I：

10.1016/0004-6981(85)90257-4

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Chamber experiments were conducted to study the aerosol products from the ozonolysis of the major atmospheric monoterpenes; alpha -pinene, beta -pinene and limonene. It was found that the alpha -pinene-O//3 reaction produced mainly 2 prime , 2 prime -dimethyl-3 prime -acetyl cyclobutyl ethanal (pinonaldehyde), the beta -pinene-O//3 reaction, mainly, 6,6-dimethyl-bicyclo left bracket 3. 1. 1 right bracket heptan-2-one and the limonene-O//3 reaction, several unidentified products. These products were sought in forest aerosols and pinonaldehyde was detected in the atmosphere.

引用

页码：1271 / 1276

页数：6

共 10 条

[1]

GAY BW, 1977, EPA600377001B REP, P745

[2]

O'Neal H. E., 1973, INT J CHEM KINET, V5, P397, DOI DOI 10.1002/KIN.550050310

[3] VOLATILE ORGANIC MATERIAL OF PLANT ORIGIN IN ATMOSPHERE [J].

RASMUSSE.RA ;

WENT, FW .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1965, 53 (01) :215-&

[4] MOLECULAR COMPOSITION OF SECONDARY AEROSOL-PARTICLES FORMED FROM TERPENES [J].

SCHUETZLE, D ;

RASMUSSEN, RA .

JOURNAL OF THE AIR POLLUTION CONTROL ASSOCIATION, 1978, 28 (03) :236-240

[5]

SCHWARTZ W, 1974, EPA650374011

[6] ORGANIC MATTER IN THE ATMOSPHERE, AND ITS POSSIBLE RELATION TO PETROLEUM FORMATION [J].

WENT, FW .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1960, 46 (02) :212-221

[7]

Westburg H.H., 1972, CHEMOSPHERE, V4, P163

[8]

WILSON WEJ, 1972, CRCAPRACCAPA6683

[9] SEASONAL-VARIATION OF MONOTERPENES IN THE ATMOSPHERE OF A PINE FOREST [J].

YOKOUCHI, Y ;

OKANIWA, M ;

AMBE, Y ;

FUWA, K .

ATMOSPHERIC ENVIRONMENT, 1983, 17 (04) :743-750

[10]

Zimmerman P. R., 1979, EPA450479004

← 1 →