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EFFECT OF TEMPERATURE ON THE FORMATION OF PHOTOCHEMICAL OZONE IN A PROPENE NOX AIR IRRADIATION SYSTEM

被引：17
作者：
HATAKEYAMA, S
AKIMOTO, H
WASHIDA, N
机构：
[1] National Institute for Environmental Studies, Tsukuba
来源：
ENVIRONMENTAL SCIENCE & TECHNOLOGY | 1991年 / 25卷 / 11期
关键词：
D O I：
10.1021/es00023a007
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
The profile of ozone formation in a propene-NO(x)-air-irradiation system was studied at 20, 30, 40, and 50-degrees-C in order to clarify the effect of temperature. The higher the temperature, the faster the formation of ozone and the longer the duration of a high concentration of ozone. The former phenomenon was due to the effect of temperature on the stability of HOONO2, and the latter was due to faster decomposition of PAN at higher temperatures. Computer simulation was employed to realize the mechanism for those temperature effects.
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页码：1884 / 1890
页数：7
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