SYNTHESES OF NI3S2, CO9S8, AND ZNS BY THE DECOMPOSITION OF DIETHYLDITHIOCARBAMATE COMPLEXES

被引：45

作者：

CUI, H

PIKE, RD

KERSHAW, R

DWIGHT, K

WOLD, A

机构：

[1] Department of Chemistry, Brown University, Providence

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1992年 / 101卷 / 01期

关键词：

D O I：

10.1016/0022-4596(92)90206-B

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three useful sulfides, Ni3S2, Co9S8, and ZnS, have been prepared by the decomposition of their respective diethyldithiocarbamate complexes. The products were characterized by X-ray diffraction analysis, crystallite size determination, and magnetic susceptibility measurements. The problems associated with organometallic precursors for the synthesis of metal sulfides are discussed and the method is compared with the direct conversion of sulfate salts to sulfides in a controlledH2/H2S environment. © 1992 Academic Press, Inc. All rights reserved.

引用

页码：115 / 118

页数：4

共 5 条

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KERSHAW, R
PASSARETTI, JD
DWIGHT, K
WOLD, A
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