RELATIVELY FAST SOLVOLYTIC REACTIONS OF 1-ADAMANTYL MESYLATE - FURTHER DEVELOPMENT OF THE YOTS SCALE OF SOLVENT IONIZING POWER AND THE NOTS SCALE OF SOLVENT NUCLEOPHILICITY

被引：95

作者：

BENTLEY, TW

CARTER, GE

机构：

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1983年 / 48卷 / 04期

关键词：

D O I：

10.1021/jo00152a033

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

引用

页码：579 / 584

页数：6

共 39 条

[1] SOLVOLYTIC REACTIVITY OF 1-TRIFLUOROMETHYL-1-PHENYLETHYL TOSYLATE - FORMATION OF A HIGHLY DESTABILIZED CARBONIUM-ION [J].

ALLEN, AD ;

JANSEN, MP ;

KOSHY, KM ;

MANGRU, NN ;

TIDWELL, TT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (01) :207-211

[2]

Bentley T.W., 1977, ADV PHYS ORG CHEM, V14, P32

[3] CRITICAL COMMENTS ON THE INTERPRETATION OF HEAT-CAPACITIES OF ACTIVATION AND ON THE EXPERIMENTAL-EVIDENCE FOR OTHER RECENT MECHANISTIC PROPOSALS FOR SOLVOLYSES OF TERT-BUTYL HALIDES IN WATER AND IN BINARY AQUEOUS MIXTURES [J].

BENTLEY, TW ;

CARTER, GE .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1982, 78 :1633-1639

[4] THE SN2-SN1 SPECTRUM .3. SOLVOLYSES OF SECONDARY AND TERTIARY ALKYL SULFONATES IN FLUORINATED ALCOHOLS - FURTHER EVIDENCE FOR THE SN2 (INTERMEDIATE) MECHANISM [J].

BENTLEY, TW ;

BOWEN, CT ;

MORTEN, DH ;

SCHLEYER, PV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (18) :5466-5475

[5] EVIDENCE AGAINST APPRECIABLE INTERNAL ION-PAIR RETURN IN THE SOLVOLYSES OF TERTIARY ALIPHATIC HALIDES - MEASUREMENT OF ALPHA-METHYL-HYDROGEN RATE RATIOS IN HEXAFLUOROPROPAN-2-OL-WATER [J].

BENTLEY, TW ;

BOWEN, CT ;

PARKER, W ;

WATT, CIF .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1980, (08) :1244-1252

[6] THE SN2-SN1 SPECTRUM .4. THE SN2 (INTERMEDIATE) MECHANISM FOR SOLVOLYSES OF TERT-BUTYL CHLORIDE - A REVISED Y-SCALE OF SOLVENT IONIZING POWER BASED ON SOLVOLYSES OF 1-ADAMANTYL CHLORIDE [J].

BENTLEY, TW ;

CARTER, GE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (21) :5741-5747

[7] SOLVOLYSES OF SECONDARY SULFONATES IN AQUEOUS ETHANOL AND ACETONE - NON-LINEAR MY RELATIONSHIPS DUE TO LEAVING GROUP AND MEDIUM EFFECTS [J].

BENTLEY, TW ;

BOWEN, CT ;

BROWN, HC ;

CHLOUPEK, FJ .

JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (01) :38-42

[8] SN2-SN1 SPECTRUM .1. ROLE OF NUCLEOPHILIC SOLVENT ASSISTANCE AND NUCLEOPHILICALLY SOLVATED ION-PAIR INTERMEDIATES IN SOLVOLYSES OF PRIMARY AND SECONDARY ARENESULFONATES [J].

BENTLEY, TW ;

SCHLEYER, PV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (24) :7658-7666

[9]

BENTLEY TW, 1982, 6TH IUPAC C LOUV

[10]

BENTLEY TW, 1978, J CHEM SOC P2, P558

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