HIGHLY DIASTEREOSELECTIVE ADDITION-REACTIONS OF A RADICAL DERIVED FROM A BETA-ETHOXYCARBONYL SULFOXIDE

被引：38

作者：

BECKWITH, ALJ

HERSPERGER, R

WHITE, JM

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 17期

关键词：

D O I：

10.1039/c39910001151

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 1-ethoxycarbonyl-1-p-tolylsulphinylethyl radical 2, generated by iodine abstraction from 1, adds to the alkenic bond in allyltriphenylstannane or in hex-1-ene with very high diastereoselectivity (> 98%).

引用

页码：1151 / 1152

页数：2

共 15 条

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