POLYIMIDES WITH ALICYCLIC DIAMINES .1. SYNTHESES AND THERMAL-PROPERTIES

The polyaddition reactions of alicyclic diamines such as 1,4-diaminocyclohexane (1,4-CHDA) or 4,4'-diaminodicyclohexylmethane (DCHM) and configurational isomers of 1,4-CHDA or DCHM with tetracarboxylic aromatic anhydrides in aprotic solvents were carried out to prepare high molecular weight poly (amic acid) s. Through the thermal imidization of poly (amic acid) s, several flexible polyimide films were prepared. Because of the stiffness of the alicyclic moieties in diamines, the resulting polyimides exhibit high glass transition temperatures (220-340-degrees-C) almost similar to those for corresponding aromatic polyimides which have phenylene groups in place of cyclohexyl groups, and show good thermal stability. The partial crystallization was observed for polyimides with trans-cyclohexyl moiety during the heating in differential scanning calorimetry and ascertained by wide-angle x-ray diffraction. Thus, the inhibition of the occurrence of charge transfer in polyimides is accomplished by introducing alicyclic diamines in place of aromatic diamines without reducing their thermal stability. (C) 1993 John Wiley & Sons, Inc.