CLUSTER CHEMISTRY .97. SOME UNUSUAL COMPLEXES OBTAINED FROM REACTIONS OF RU-3(MU-DPPM)(CO)(10) AND C-7 OR C-8 HYDROCARBONS

被引：14

作者：

BRUCE, MI ^{[1
]}

HINCHLIFFE, JR ^{[1
]}

SKELTON, BW ^{[1
]}

WHITE, AH ^{[1
]}

机构：

[1] UNIV WESTERN AUSTRALIA,DEPT CHEM,NEDLANDS,WA 6009,AUSTRALIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 495卷 / 1-2期

关键词：

RUTHENIUM; CARBONYL; ALKYNE LIGANDS; CYCLOHEPTATRIENE; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(95)05407-G

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Among the products of reactions between Ru-3(mu-dppm)(CO)(10) and impure cycloheptatriene were Ru-3(mu(3)-C7H8)(mu-dppm)(CO)(7) (3a) and two isomers of Ru-3(mu(3)-C8H10)(mu-dppm)(CO)(7) (2b and 3b). On the basis of crystallographic studies, 2b is judged to be Ru-3(mu-H)(2)(mu(3)-C(7)H(5)Me)(mu-dppm)(CO)(7), containing the novel norbornenyne ligand, while complexes 3 contain cyclopentenylacetylide ligands. None of these were obtained when purified cycloheptatriene was used.

引用

页码：141 / 148

页数：8

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