SYNTHESIS OF SUBSTITUTED ALPHA-METHYLENE LACTAMS BY RHODIUM-CATALYZED CARBONYLATION OF ACETYLENIC AMINES

被引:24
作者
CAMPI, EM
CHONG, JM
JACKSON, WR
VANDERSCHOOT, M
机构
[1] MONASH UNIV,DEPT CHEM,CLAYTON,VIC 3168,AUSTRALIA
[2] UNIV WATERLOO,DEPT CHEM,WATERLOO N2L 3G1,ON,CANADA
关键词
D O I
10.1016/S0040-4020(01)86969-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Reactions of gamma- and beta-aminoalkynes, (2) and (5) with hydrogen and carbon monoxide in the presence of rhodium catalysts give substituted alpha-methylene-2-piperidinones (7) and 2-pyrrolidinones (11).
引用
收藏
页码:2533 / 2542
页数:10
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