REACTION OF 1,1-DIMETHYLHYDRAZINE WITH GASEOUS CHLORAMINE

被引：31

作者：

UTVARY, K

SISLER, HH

机构：

[1] Department of Chemistry, University of Florida, Gainesville

来源：

INORGANIC CHEMISTRY | 1968年 / 7卷 / 04期

关键词：

D O I：

10.1021/ic50062a015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 1,1-dimethylhydrazine with chloramine or a mixture of chloramine and ammonia yields 2,2-dimethyltriazanium chloride, [(CH3)2N(NH2)2] +Cl−. The sole solid by-product in this reaction is ammonium chloride, apparently formed by the decomposition of chloramine on the solid reaction product and possibly also by catalytic decomposition of chloramine by dimethylhydrazine. The dependence of the formation of 2,2-dimethyltriazanium chloride upon temperature, concentration, and reaction time has been investigated. Hydrogen-1 nmr and infrared spectroscopic evidence for the struc¬ture is given. © 1968, American Chemical Society. All rights reserved.

引用

页码：698 / &

共 9 条

[1]

COLLIER F, 1959, J AMER CHEM SOC, V83, P6177

[2] REACTION OF DIPHENYLCHLOROPHOSPHINE WITH AMMONIA-FREE CHLORAMINE [J].