MESO-(TETRAPHENYLPORPHINATO)MANGANESE(III)-TETRACYANOETHENIDE, [MNIIITPP]=CIRCLE-PLUS[TCNE] CIRCLE-MINUS - A NEW STRUCTURE-TYPE LINEAR-CHAIN MAGNET WITH A TC OF 18-K

被引：229

作者：

MILLER, JS

CALABRESE, JC

MCLEAN, RS

EPSTEIN, AJ

机构：

[1] OHIO STATE UNIV,DEPT CHEM,COLUMBUS,OH 43210

[2] OHIO STATE UNIV,DEPT PHYS,COLUMBUS,OH 43210

来源：

ADVANCED MATERIALS | 1992年 / 4卷 / 7-8期

关键词：

D O I：

10.1002/adma.19920040710

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Communication: Cooperative magnetic interactions in molecular materials at room temperature are the goal of much interdisciplinary research. The title compound is shown to have a T(c) of 18K and to be of a new structural type which makes it a suitable model for the previously reported, disordered, infusible V(TCNE)x which is a room-temperature magnet. The synthesis and structure of the new material are discussed.

引用

页码：498 / 501

页数：4

共 28 条

[1]

BRODERICK WE, 1990, SCIENCE, V249, P410

[2]

BUCHACHENKO AL, 1990, USP KHIM+, V59, P529

[3]

BUCHACHENKO AL, 1990, RUSS CHEM REV, V59, P307

[4]

CHITTAPEDDI SR, 1987, PHYS REV LETT, V22, P2695

[5] CRYSTAL AND MOLECULAR-STRUCTURE OF THE CHARGE-TRANSFER SALT OF DECAMETHYLCOBALTOCENE AND TETRACYANOETHYLENE (2-1) - ([CO(C5ME5)2]+)2[(NC)2CC(CN)2]2- - THE ELECTRONIC-STRUCTURES AND SPECTRA OF [TCNE]0, [TCNE]1-, [TCNE]2- [J].

DIXON, DA ;

MILLER, JS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (12) :3656-3664

[6]

DRILLON M, 1987, PHYS LETT A, V68, P89

[7]

DULOG L, 1990, NACHR CHEM TECH LAB, V38, P448

[8]

EPSTEIN AJ, IN PRESS P NOBEL S

[9]

ISHIDA H, 1989, ENCY POLYM SCI TECHN, P446

[10]

KAHN O, 1987, STRUCT BOND, V68, P89

← 1 2 3 →