SYNTHESIS AND MOLECULAR-STRUCTURE OF [7]CIRCULENE

被引：121

作者：

YAMAMOTO, K ^{[1
]}

HARADA, T ^{[1
]}

OKAMOTO, Y ^{[1
]}

CHIKAMATSU, H ^{[1
]}

NAKAZAKI, M ^{[1
]}

KAI, Y ^{[1
]}

NAKAO, T ^{[1
]}

TANAKA, M ^{[1
]}

HARADA, S ^{[1
]}

KASAI, N ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1988年 / 110卷 / 11期

关键词：

MOLECULES - Structure - ORGANIC COMPOUNDS - Synthesis;

D O I：

10.1021/ja00219a036

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The polycyclic aromatic compound with a circular arrangement of seven benzene rings, circulene was prepared by treatment of 1,16-dehydro-2,15-diformylhexahelicene with low-valent titanium. Its unusual saddle-shaped structure with C//2 symmetry was supported by its X-ray analysis. Preparation, X-ray analysis, and optical stability of dehydro circulene derivatives were also reported.

引用

页码：3578 / 3584

页数：7

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