NOVEL SYNTHESIS OF A MIXED PHOSPHONIC ANHYDRIDE - A ROUTE TO CARBOXYLIC-ACID DERIVATIVES FROM A METHYL KETONE

被引：1

作者：

BROWN, P

OHANLON, PJ

机构：

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 51期

关键词：

D O I：

10.1016/0040-4039(94)88527-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Conversion of a methyl ketone to the kinetic enol phosphate followed by ozonolysis provides a novel synthesis of a mixed phosphonic anhydride. This can either be isolated, or reacted in situ with nucleophiles to afford the corresponding acid derivatives.

引用

页码：9619 / 9622

页数：4