HYDROGEN-BONDING OF N-MONOSUBSTITUTED AMIDES - IR AND NMR-STUDY OF N-BUTYLBENZAMIDES

被引:14
作者
NIKOLIC, AD [1 ]
ROZSATARJANI, M [1 ]
KOMAROMI, A [1 ]
CSANADI, J [1 ]
PETROVIC, SD [1 ]
机构
[1] UNIV BELGRADE, FAC TECHNOL, YU-11000 BELGRADE, NORTH MACEDONIA
关键词
D O I
10.1016/0022-2860(92)87008-J
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The self-association through hydrogen bonding of N-butylbenzamides has been studied by infrared spectroscopy in carbon tetrachloride, chloroform and benzene. The spectroscopic characteristics and thermodynamic parameters for the self-association have been determined. Also, the carbon tetrachloride and chloroform solutions of the amides have been studied by H-1 NMR spectroscopy. The equilibrium constants for self-association obtained by NMR technique are in good agreement with the corresponding values from infrared measurements.
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页码:49 / 54
页数:6
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