SYNTHESIS AND ANODIC POLYMERIZATION OF AN L-CYSTINE DERIVATIZED PYRROLE - COPOLYMERIZATION WITH A TETRAALKYLAMMONIUM PYRROLE ALLOWS REDUCTION OF THE CYSTINYL FILM TO A CYSTEINYL STATE THAT BINDS ELECTROACTIVE (FE4S4)2+ CENTERS

被引：21

作者：

PICKETT, CJ ^{[1
]}

RYDER, KS ^{[1
]}

MOUTET, JC ^{[1
]}

机构：

[1] UNIV JOSEPH FOURIER,CRNS,ELECTROCHIM ORGAN & PHOTOCHIM REDOX LAB,GRENOBLE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 09期

关键词：

D O I：

10.1039/c39920000694

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cystine derivatised pyrrole I is synthesised and stable neutral polymers or cationic copolymers are produced by anodic oxidation at Pt and glassy carbon electrodes; chemical reduction of cystine-tetraalkylammonium co-functionalised films gives ion-exchange polymers with pendant cysteinyl groups and these thiolate films tightly bind {Fe4S4}2+ centres giving an electrode-polymer assembly with electroactive, cysteinyl ligated, ferredoxin-like units.

引用

页码：694 / 697

页数：4

共 4 条

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