REGIOSELECTIVITY CONTROL IN METAL HYDRIDE REDUCTIONS OF SUBSTITUTED MALEIC ANHYDRIDES

被引：32

作者：

KAYSER, MM ^{[1
]}

BREAU, L ^{[1
]}

ELIEV, S ^{[1
]}

MORAND, P ^{[1
]}

IP, HS ^{[1
]}

机构：

[1] UNIV OTTAWA,DEPT CHEM,OTTAWA K1N 9B4,ONTARIO,CANADA

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1986年 / 64卷 / 01期

关键词：

Maleic anhydride - Hydrides;

D O I：

10.1139/v86-018

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A systematic study of reductions of unsymmetrically substituted maleic anhydrides by a variety of metal hydride reagents indicates that the high regioselectivity observed in these reactions is controlled chiefly by electronic factors.

引用

页码：104 / 109

页数：6

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