CATALYTIC CONVERSION OF ALKENES INTO ALLYLIC ETHERS AND ESTERS USING DISELENIDES HAVING INTERNAL TERTIARY-AMINES

被引:67
作者
IWAOKA, M [1 ]
TOMODA, S [1 ]
机构
[1] UNIV TOKYO,COLL ARTS & SCI,DEPT CHEM,MEGURO KU,TOKYO 153,JAPAN
关键词
D O I
10.1039/c39920001165
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
2,2'-Diselenobis {N,N-di[2-(2-pyridyl)ethyl]benzylamine} 1 with copper(II) nitrate or 2,2'-diselenobis(N-cyclohexyl-N-methylbenzylamine) 2 catalyses the conversion of alkenes 3 into oxygenated allylic compounds 4 both in methanol and in acetic acid in the presence of sodium persulfate as an oxidizing agent.
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页码:1165 / 1167
页数:3
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