A MONONUCLEAR TERT-BUTYLIMIDO COMPLEX OF NIOBIUM(V) - X-RAY CRYSTAL-STRUCTURE OF [PH3PCH2PH][NB(NBU(T))CL4(PY)].CH2CL2

被引：16

作者：

CLEGG, W ^{[1
]}

ERRINGTON, RJ ^{[1
]}

HOCKLESS, DCR ^{[1
]}

REDSHAW, C ^{[1
]}

机构：

[1] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

来源：

POLYHEDRON | 1991年 / 10卷 / 16期

关键词：

D O I：

10.1016/S0277-5387(00)86061-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

NbOCl3 reacts with Bu(t)NH2 in the presence of [Ph3PCH2Ph]Cl and pyridine in refluxing toluene to give the mononuclear anion [Nb(NBu(t))Cl4(py)]-, which has been structurally characterized by X-ray crystallography.

引用

页码：1959 / 1961

页数：3

共 12 条

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[4] AN ORGANOIMIDO MOLYBDENUM(VI) COMPLEX - PREPARATION AND STRUCTURE OF (PARA-TOLYLN)-MOCL4(THF)
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[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (17) : 1184 - 1185
[5] POLYTUNGSTATE SELF-ASSEMBLY - STRUCTURES OF THE NEW OXOANIONS, [W4(NBUT)4O4CL10]2- AND [W6O14CL10]2-
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[J]. POLYHEDRON, 1989, 8 (13-14) : 1788 - 1789
[6] Clegg W., UNPUB
[7] A NEW DOUBLE-BOND METATHESIS REACTION - CONVERSION OF AN NB=NB AND AN N=N BOND INTO 2 NB=N BONDS
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[8] ERRINGTON RJ, UNPUB
[9] PREPARATION AND REACTIVITY OF TUNGSTEN(VI) METALLACYCLOBUTANE COMPLEXES - SQUARE PYRAMIDS VERSUS TRIGONAL BIPYRAMIDS
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[10] [TACL(MU-CL)(NBU-TERT)(NHBU-TERT)(NH2BU-TERT)]2 - A TANTALUM(V) COMPLEX CONTAINING TERMINAL IMIDO, AMIDO, AND AMINO LIGANDS
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