BORON-TRIFLUORIDE ETHERATE MEDIATED 1,4-ADDITION OF (1-ALKYNYL)DIISOPROPOXYBORANES TO ALPHA,BETA-UNSATURATED KETONES - A CONVENIENT NEW ROUTE TO 3-ALKYNYL KETONE SYNTHESIS

被引：28

作者：

FUJISHIMA, H ^{[1
]}

TAKADA, E ^{[1
]}

HARA, S ^{[1
]}

SUZUKI, A ^{[1
]}

机构：

[1] HOKKAIDO UNIV, FAC ENGN, DEPT APPL CHEM, SAPPORO, HOKKAIDO 060, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 04期

关键词：

D O I：

10.1246/cl.1992.695

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of BF3 etherate, (1-alkynyl)diisopropoxyboranes react with alpha,beta-unsaturated ketones to give 1,4-addition products selectively in good yields.

引用

页码：695 / 698

页数：4

共 8 条

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