UTILIZATION OF ME3SISNBU3 IN ORGANIC-SYNTHESIS .1. GENERATION OF A STANNYL ANION FROM ME3SISNBU3 AND R4NX

被引：22

作者：

MORI, M ^{[1
]}

KANETA, N ^{[1
]}

ISONO, N ^{[1
]}

SHIBASAKI, M ^{[1
]}

机构：

[1] UNIV TOKYO,FAC PHARMACOL SCI,BUNKYO KU,TOKYO 113,JAPAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 455卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)80407-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A metal free stannyl anion generated from Me3SiSnBu3 and R4NX in DMF reacted with an aryl halide bearing carbonyl group to produce an aryl anion via the so-called halogen-metal exchange process, which reacted with a carbonyl group to afford a cyclized product in good yield.

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页码：255 / 260

页数：6

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