PRECURSOR MONOMER ROUTE - A NOVEL CONCEPT FOR PRODUCING HIGHLY CONDUCTIVE POLYPYRROLE FILMS

被引：8

作者：

VANDIJK, H ^{[1
]}

AAGAARD, O ^{[1
]}

SCHELLEKENS, R ^{[1
]}

机构：

[1] DSM RES & PATENTS,POB 18,6160 MD GELEEN,NETHERLANDS

来源：

SYNTHETIC METALS | 1993年 / 55卷 / 2-3期

关键词：

D O I：

10.1016/0379-6779(93)90204-A

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Heating of micro porous UHMW-PE films, impregnated with a solution of pyrrole-2-carboxylic acid and FeCl3, results in tough and flexible films with conductivities up to 10 S/cm. Within the films a continuous network of polypyrrole is present as a coating layer on the micro fibrils of polyethylene. By triggering of the reaction via thermochemical, oxidative decarboxylation of the pyrrole-2-carboxylic precursors, a controlled and efficient polymerisation is provided, resulting in a fast and continuous production process.

引用

页码：1085 / 1090

页数：6