HYDROXYSELENATION OF ALLYLIC ALCOHOLS

被引：20

作者：

COOPER, MA ^{[1
]}

WARD, AD ^{[1
]}

机构：

[1] UNIV ADELAIDE,DEPT CHEM,ADELAIDE,SA 5005,AUSTRALIA

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 13期

关键词：

D O I：

10.1016/0040-4039(95)00247-A

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hydroxyselenation of terminal or cyclic allylic alcohols occurs with high regio- and stereoselectivity to give beta,beta'-dihydroxyphenylselenated adducts in high yields. A mechanism for this selectivity is proposed. The utility of these adducts is illustrated by the conversion of the hydroxyselenide (9a) to the epoxide (11) via the intermediacy of a selenone.

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页码：2327 / 2330

页数：4

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