CYCLIC VOLTAMMETRY IN TRIFLUOROMETHANESULFONIC ACID - FACILE ELECTROCHEMISTRY UP TO +3 V

被引：5

作者：

BERNHARD, P ^{[1
]}

DIAB, H ^{[1
]}

LUDI, A ^{[1
]}

机构：

[1] INST ANORGAN CHEM,CH-3000 BERN 9,SWITZERLAND

来源：

INORGANICA CHIMICA ACTA | 1990年 / 173卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)91056-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A 0.1 M solution of sodium trifluoromethanesulfonate in neat trifluoromethanesulfonic (triflic) acid is used as solvent in cyclic voltammetry. Working, counter and quasi-reference electrodes consist of glassy carbon, platinum and silver wire, respectively. Reversible voltammograms between +0.4 and +3 V versus NHE are recorded at 0 °C with scan rates around 100 mV s-1 and are calibrated against Ru- (bpy)33+/2+. Redox processes for a series of coordination compounds involving high oxidation states are studied without complicating chemical reactions. © 1990.

引用

页码：65 / 68

页数：4

共 17 条

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