SYNTHESIS AND PHOTOLYSIS OF MIXED COPPER(I) COMPLEXES WITH THIONES AND TRI-PARA-TOLYLPHOSPHINE OR TRIPHENYLPHOSPHINE - X-RAY CRYSTAL-STRUCTURE OF BIS[COPPER(I)(1,3-THIAZOLIDINE-2-THIONE) (TRI-PARA-TOLYLPHOSPHINE)CHLORIDE]

被引:30
作者
HADJIKAKOU, SK [1 ]
ASLANIDIS, P [1 ]
KARAGIANNIDIS, P [1 ]
机构
[1] UNIV THESSALONIKI,FAC CHEM,DEPT GEN & INORGAN CHEM,POB 135,GR-54006 SALONIKA,GREECE
关键词
D O I
10.1016/S0277-5387(00)86911-9
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reaction of [Cu(PR3)Cl]4 [where PR3 = tri-p-tolylphosphine (tptp), or triphenylphosphine(tpp)] with several heterocyclic thiones (L) yields binuclear complexes of the general formula [Cu(PR3)(L)Cl]2 [L = 1,3-thiazolidine-2-thione (tzdtH), benz-1,3-thiazoline-2-thione (bztztH), dithiouracil (dtu), purine-6-thione (pur6SH) and thiourea (tu)]. Irradition of the complexes, in chloroform, methanol and acetonitrile solutions, caused phosphine evolution while the Cu2S2 core remained intact. The crystal structure of [Cu(tptp)(tzdtH)Cl]2 has been established by single-crystal X-ray diffraction methods. In the Cu2S2 core the Cu-S bond lengths are 2.386(1) and 2.470(1) angstrom. The Cu-P and Cu-Cl distances are 2.222(1) and 2.283(1) angstrom, respectively.
引用
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页码:935 / 940
页数:6
相关论文
共 28 条
  • [1] [Anonymous], 1974, INT TABLES XRAY CRYS, VIV
  • [2] Bellamy L.J., 1966, INFRARED SPECTRA COM
  • [3] COLEMAN JS, 1970, INORG CHEM, V9, P105
  • [4] COMPLEXES OF COPPER (I) WITH TRIPHENYLPHOSPHINE
    COSTA, G
    REISENHOFER, E
    STEFANI, L
    [J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1965, 27 (12): : 2581 - +
  • [5] COPPER(I) HALIDE-COMPLEXES OF IMIDAZOLE THIONES - CRYSTAL-STRUCTURE OF DIMERIC MONOCHLORO BIS(1-METHYLIMIDAZOLINE-2-THIONE) COPPER(I)
    CREIGHTON, JR
    GARDINER, DJ
    GORVIN, AC
    GUTTERIDGE, C
    JACKSON, ARW
    RAPER, ES
    SHERWOOD, PMA
    [J]. INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 103 (02): : 195 - 205
  • [6] SUBSTITUENT EFFECTS AND THE PHOTO-LUMINESCENCE OF CU(PPH3)2(NN)+ SYSTEMS
    DELPAGGIO, AA
    MCMILLIN, DR
    [J]. INORGANIC CHEMISTRY, 1983, 22 (04) : 691 - 692
  • [7] SYNTHESIS AND PHOTOCHEMICAL STUDY OF CU(I) COMPLEXES WITH TRI-P-TOLYLPHOSPHINE AND HETEROCYCLIC THIONES - THE CRYSTAL-STRUCTURE OF [CUCL(PYMTH)(P-CH3C6H4)3P]2
    KARAGIANNIDIS, P
    HADJIKAKOU, SK
    ASLANIDIS, P
    HOUNTAS, A
    [J]. INORGANICA CHIMICA ACTA, 1990, 178 (01) : 27 - 34
  • [8] NEW CLASS OF CU(I) COMPLEXES WITH 2-THIOXOHEXAMETHYLENEIMINE (TCLH) AND GROUP-VA DONORS - CRYSTAL-STRUCTURE OF [CU(TCLH)2(ASPH3)BR]
    KARAGIANNIDIS, P
    AKRIVOS, PD
    MENTZAFOS, D
    TERZIS, A
    [J]. INORGANICA CHIMICA ACTA, 1991, 181 (02) : 263 - 267
  • [9] MONONUCLEAR AND BINUCLEAR CU(I) COMPLEXES WITH METAL SULFUR LIGATION
    KARAGIANNIDIS, P
    ASLANIDIS, P
    KESSISSOGLOU, DP
    [J]. INORGANICA CHIMICA ACTA, 1989, 156 (01) : 47 - 56
  • [10] CU(I) COMPLEXES WITH HETEROCYCLIC THIONES AND TRIPHENYLPHOSPHINE AS LIGANDS - THE CRYSTAL-STRUCTURE OF [CU(TZDTH)2(PPH3)2]NO3
    KARAGIANNIDIS, P
    ASLANIDIS, P
    PAPASTEFANOU, S
    MENTZAFOS, D
    HOUNTAS, A
    TERZIS, A
    [J]. INORGANICA CHIMICA ACTA, 1989, 156 (02) : 265 - 270