OXIDATION OF PRIMARY AMINES OVER VANADIUM SILICALITE MOLECULAR-SIEVE, VS-1

被引：31

作者：

REDDY, JS

SAYARI, A

机构：

[1] UNIV LAVAL,DEPT CHEM ENGN,ST FOY G1K 7P4,PQ,CANADA

[2] UNIV LAVAL,CERPIC,ST FOY G1K 7P4,PQ,CANADA

来源：

CATALYSIS LETTERS | 1994年 / 28卷 / 2-4期

关键词：

MILD OXIDATION; AMINES; VANADIUM SILICALITES; VS-1;

D O I：

10.1007/BF00806055

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The mild oxidation of various primary amines with diluted hydrogen peroxide has been studied over vanadium silicalite molecular sieve, VS-1. The reaction leads to the corresponding oximes and imines. The nature of solvent was found to have a strong influence on the product selectivity. The use of chloroform favors the formation of nitroalkanes. Under similar conditions primary amines with no alpha-hydrogen, such as aniline, were oxidized mainly to the corresponding azoxy derivatives.

引用

页码：263 / 267

页数：5

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