CATALYTIC ASYMMETRIC ADDITION OF ORGANOLITHIUMS TO ALDIMINES

被引:82
作者
TOMIOKA, K [1 ]
INOUE, I [1 ]
SHINDO, M [1 ]
KOGA, K [1 ]
机构
[1] TANABE SEIYAKU CO LTD,ORGAN CHEM RES LAB,TODA,SAITAMA 335,JAPAN
关键词
D O I
10.1016/0040-4039(91)80698-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An asymmetric 1,2-addition of organolithiums to imines (1) was catalyzed by a substoichiometric amount (0.05 approximately 0.3 equivalent) of a chiral aminoether (2) to provide the corresponding optically active amines (3).
引用
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页码:3095 / 3098
页数:4
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