CATALYTIC ASYMMETRIC ADDITION OF ORGANOLITHIUMS TO ALDIMINES

被引：82

作者：

TOMIOKA, K ^{[1
]}

INOUE, I ^{[1
]}

SHINDO, M ^{[1
]}

KOGA, K ^{[1
]}

机构：

[1] TANABE SEIYAKU CO LTD,ORGAN CHEM RES LAB,TODA,SAITAMA 335,JAPAN

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 26期

关键词：

D O I：

10.1016/0040-4039(91)80698-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An asymmetric 1,2-addition of organolithiums to imines (1) was catalyzed by a substoichiometric amount (0.05 approximately 0.3 equivalent) of a chiral aminoether (2) to provide the corresponding optically active amines (3).

引用

页码：3095 / 3098

页数：4

共 10 条

[1] Bosnich B., 1986, ASYMMETRIC CATALYSIS
[2] ENANTIOSELECTIVE ADDITION OF DIALKYLZINCS TO ALDEHYDES PROMOTED BY CHIRAL AMINO-ALCOHOLS - MECHANISM AND NONLINEAR EFFECT
KITAMURA, M
OKADA, S
SUGA, S
NOYORI, R
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (11) : 4028 - 4036
[3] CHIRAL CATALYSIS OF ADDITIONS OF ALKYLLITHIUMS TO ALDEHYDES
MAZALEYRAT, JP
CRAM, DJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (15) : 4585 - 4586
[4] Morrison J. D., 1983, ASYMMETRIC SYNTHESIS, V1-5
[5] ASYMMETRIC AMPLIFYING PHENOMENA IN ENANTIOSELECTIVE ADDITION OF DIETHYLZINC TO BENZALDEHYDE
OGUNI, N
MATSUDA, Y
KANEKO, T
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (23) : 7877 - 7878
[6] CATALYTIC ASYMMETRIC INDUCTION - HIGHLY ENANTIOSELECTIVE ADDITION OF DIALKYLZINCS TO ALDEHYDES USING CHIRAL PYRROLIDINYLMETHANOLS AND THEIR METAL-SALTS
SOAI, K
OOKAWA, A
KABA, T
OGAWA, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (23) : 7111 - 7115
[7] ENANTIOSELECTIVE ALKYLATION OF ALDEHYDE CATALYZED BY DISULFONAMIDE-TI(O-ISO-PR)4-DIALKYL ZINC SYSTEM
TAKAHASHI, H
KAWAKITA, T
YOSHIOKA, M
KOBAYASHI, S
OHNO, M
[J]. TETRAHEDRON LETTERS, 1989, 30 (50) : 7095 - 7098
[8] ASYMMETRIC ORGANOLITHIUM ADDITIONS TO IMINES
TOMIOKA, K
INOUE, I
SHINDO, M
KOGA, K
[J]. TETRAHEDRON LETTERS, 1990, 31 (46) : 6681 - 6684
[9] TOMIOKA K, 1990, SYNTHESIS-STUTTGART, P541
[10] NOVEL STRATEGY OF USING A C-2 SYMMETRIC CHIRAL DIETHER IN THE ENANTIOSELECTIVE CONJUGATE ADDITION OF AN ORGANO-LITHIUM TO AN ALPHA,BETA-UNSATURATED ALDIMINE
TOMIOKA, K
SHINDO, M
KOGA, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (21) : 8266 - 8268

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