DETECTION OF NOE INTERACTION BETWEEN COMPONENTS OF ORGANIC PI-COMPLEXES

被引：7

作者：

HOFFMAN, RE

RABINOVITZ, M

机构：

[1] Margaret Thatcher Laboratory, Department of Organic Chemistry, Hebrew University of Jerusalem, Jerusalem

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 1993年 / 31卷 / 11期

关键词：

H-1; NMR; NOE; INTERMOLECULAR NOE; PI-COMPLEXES; CHARGE-TRANSFER COMPLEXES;

D O I：

10.1002/mrc.1260311115

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Homonuclear H-1,H-1 NOE effects were observed for pi charge-transfer complexes of 2,4,6-trinitrotoluene (TNT) with aromatic hydrocarbons using a 1D-NOESY experiment. The intensity of the NOEs indicates that the structure in solution is analogous to that in the solid state as determined by x-ray crystallography.

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页码：1031 / 1033

页数：3

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