SYNTHESIS AND X-RAY STRUCTURES OF BIS(3,5-DI-TERT-BUTYLCATECHOLATO)(PHENANTHROLINE)VANADIUM(IV) AND ITS VANADIUM(V) ANALOG [V(DTBC)2(PHEN)][SBF6]

被引：31

作者：

KABANOS, TA

WHITE, AJP

WILLIAMS, DJ

WOOLLINS, JD

机构：

[1] UNIV LONDON IMPERIAL COLL SCI & TECHNOL,DEPT CHEM,LONDON SW7 2AY,ENGLAND

[2] UNIV IOANNINA,DEPT CHEM,INORGAN & ANALYT CHEM SECT,GR-45110 IOANNINA,GREECE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 01期

关键词：

D O I：

10.1039/c39920000017

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bis(3,5-di-tert-butylcatecholato)(phenanthroline)vanadium(iv) 1 is prepared, and oxidised with silver hexafluoroantimonate to give its vanadium(v) analogue 2; both complexes are characterised by X-ray crystallography revealing significant differences in their coordination geometry.

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页码：17 / 18

页数：2

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